CEA, LETI, Minatec Campus, Grenoble, F-38054, France, Université Grenoble Alpes, Grenoble, F-38000, France,

Thick Ge layers grown on Si(0 0 1) are handy for the production of GeOI wafers, as templates for the epitaxy of III-V and GeSn-based heterostructures and so on. Perfecting their crystalline quality would enable to fabricate suspended Ge micro-bridges with extremely high levels of tensile strain (for mid IR lasers). In this study, we have used a low temperature (400 °C)/high temperature (750 °C) approach to deposit with GeH4 various thickness Ge layers in the 0.5 µm – 5 µm range. They were submitted afterwards to short duration thermal cycling under H2 (in between 750 °C and 875–890 °C) to lower the Threading Dislocation Density (TDD). Some of the thickest layers were partly etched at 750 °C with gaseous HCl to recover wafer bows compatible with device processing later on. X-ray Diffraction (XRD) showed that the layers were slightly tensile-strained, with a 104.5–105.5% degree of strain relaxation irrespective of the thickness. The surface was cross-hatched, with a roughness slightly decreasing with the thickness, from 2.0 down to 0.8 nm. The TDD (from Omega scans in XRD) decreased from 8 × 107 cm?2 down to 107 cm?2 as the Ge layer thickness increased from 0.5 up to 5 µm. The lack of improvement when growing 5 µm thick layers then etching a fraction of them with HCl over same thickness layers grown in a single run was at variance with Thin Solid Films 520, 3216 (2012). Low temperature HCl defect decoration confirmed those findings, with (i) a TDD decreasing from slightly more 107 cm?2 down to 5 × 106 cm?2 as the Ge layer thickness increased from 1.3 up to 5 µm and (ii) no TDD hysteresis between growth and growth then HCl etch-back. © 2018

A1. Defects, A1. Stresses, A1. Surface structure, A3. Chemical vapor deposition processes, B2. Germanium silicon alloys

Chemical vapor deposition, Chlorine compounds, Film growth, Germanium, Germanium alloys, Si-Ge alloys, Silicon alloys, Silicon wafers, Strain relaxation, Temperature, X ray diffraction, Chemical vapor deposition process, Crystalline quality, Device processing, Low temperatures, Short durations, Strain relaxed buffers, Thickness layers, Threading dislocation densities, Tensile strain